Strontium Isotopic evidence for Heterogeneous sediment-water interactions in inland groundwater of the western Bengal Basin
Abstract
The diverse geochemical composition of Ganga-Brahmaputra floodplain sediments found in the inland aquifers of the Bengal Basin, and their impact on groundwater chemistry over a seasonal timescale, has been poorly investigated yet. This study combines seasonal groundwater geochemistry with isotope-based mass-balance modelling to constrain the controls on dissolved Sr and 87Sr/86Sr in depth-bound inland groundwater from the western Bengal Basin (West Bengal, India) located within the Ganga (Hooghly) floodplain. To further understand the spatial variations in the inland groundwater composition across the Bengal floodplain, the present groundwater database has been compared with available inland groundwater data from the eastern Bengal Basin (Bangladesh) located in both the Ganga and Brahmaputra drainage basins. The shallow groundwater in western Bengal Basin exhibits variable hydrogeochemistry and radiogenic 87Sr/86Sr with limited seasonal variability; however, showing higher solute loads during pre-monsoon period. Comparing with available geochemical data on the Ganga River bedload sediments-water, we suggest detrital radiogenic calcite dissolution (74 - 93%) from the Ganga floodplain sediments and a subordinate localized contribution from silicate mineral weathering may drive heterogeneous Sr release with radiogenic 87Sr/86Sr in the seasonal shallow groundwater, which may further undergo secondary interactions with exchangeable clay-sediment fractions.
Advancing Palaeoclimate Reconstructions using Triple Oxygen Isotopes in Carbonates
Abstract
The challenge in predicting monsoon is difficult to overcome by relying on instrumental data from only the past few decades. Palaeomonsoon reconstructions help us understand and predict the sensitivity and response of monsoon to forcings on multi-decadal-centennial timescale. Numerous palaeomonsoon reconstructions based on oxygen-18 in speleothems have been done in India to investigate the drivers of Indian Summer Monsoon Rainfall (ISMR). However, it can be difficult to deconvolve the δ18O signal into individual components, including possible kinetic isotope effects, temperature, precipitation amount, moisture source and transport, which can lead to an overstated climatic signal. In such a case, the extent to which the variability in ISMR in the instrumental period reflects natural variability, still remains debatable. In this seminar, I will discuss how triple oxygen isotope systematics can provide a way to identify kinetic effects and delineate the influencing processes. I will present results from in-house setup that have resolved the existing theoretical-experimental gap and interlaboratory inconsistencies, crucial in standardising triple oxygen measurements in carbonates. I will also present preliminary investigations of paired speleothem-dripwater samples from Indian caves.
Reconstructing Climate and Environmental Shifts in the Levantine Corridor across the Pliocene-Early Pleistocene
Abstract
The Pliocene was the last significant sustained warm period on Earth. Atmospheric carbon dioxide and global temperatures during this interval can be comparable to those modeled and proposed for the near future. Considering a similar continental and oceanic positioning to the present, it is possible to assume that the oceanic and atmospheric circulation patterns were also comparable to those of today. Current data on the Pliocene, and the transition to the cooling conditions of the Pleistocene, mostly arrive from marine archives, thus leaving the continental regions mostly barren of reliable and continuous information. Therefore, continental climate archives from this interval are highly valuable for comprehending the impact of climate change on terrestrial areas and serve as good analogues for understanding present conditions without the influence of humans.
In the present study, a multi-proxy approach was applied to both sediment cores and outcrop samples retrieved from three different lacustrine formations exposed in the Near East, which are chronologically constrained to the Pliocene and Early Pleistocene. The multi-proxy analyses indicate major fluctuations in the lakes hypsometry, transitions from anoxic to oxic conditions in the sediment-water interface, and major changes in the limnic states, indicating a response of the lake systems to changing conditions in the precipitation patterns through time. It appears that the different lakes responded to orbital-scale forcing, which may have played a key role in governing the dry-wet climate cycles in the Near East. Results from this study provide an important understanding of the hydrological conditions that may have dominated the region during a warmer climate phase, challenging previous estimations, while concurrently providing clues to the role of the climate system in greening the path of early hominin migrations out of Africa through the region.
